Charakteristische Funktionen aus deutschen Ringversuchsdaten
Die Funktion
Diese Internetseite soll die Ergebnisse der Berechnung von charakteristischen Funktionen aus deutschen Wasserringversuchsdaten zeigen. Daten deutscher Veranstalter von Wasserringversuchen (hauptsächlich AQS Baden-Württemberg) werden genutzt, um die Konzentrationsabhängigkeit der relativen Vergleichstandardabweichung darzustellen1. Eine charakteristische Funktion2-4 der folgenden Form wird genutzt, um diese Abhängigkeit zu beschreiben.
, wobei y(Dach) die relative Standardabweichung und x die Konzentration des Analyten ist.
Die Funktion wird aus mehreren, verschiedenen Datensätzen durch gewichtete Regression (kleinste Fehlerquadrate) ermittelt.
Für kleine Konzentrationen impliziert diese Funktion, dass die absolute Standardabweichung konstant und gleich α ist. Für hohe Konzentrationen wird die relative Standardabweichung als konstant und gleich β angenommen. Die Konzentration, die den Übergang von konstanter absoluter zu konstanter relativer Standardabweichung (den Bruchpunkt) beschreibt, kann aus α/β berechnet werden.
α und β werden aus Ringversuchsdaten abgeschätzt. Aufgrund von Bewertungsproblemen werden Konzentrationen nahe der Bestimmungsgrenze in Ringversuchen gewöhnlich vermieden. Deshalb ist in den meisten Fällen die Abschätzung des Parameters β möglich, aber die Schätzung von α aus Ringversuchsdaten ist oft nicht zuverlässig genug. In der nachfolgenden Tabelle werden α-Werte nur dann angegeben, wenn der Bruchpunkt über dem 1.Quartil des Datensatzes liegt, d.h. 25% der Daten unter dem Bruchpunkt liegen. In derselben Weise werden β-Werte nur dann angegeben, wenn der Bruchpunkt unterhalb des 3. Quartils des Datensatzes liegt, so dass sich 25% der Daten oberhalb des Bruchpunkts befinden.
Mögliche Anwendungen der charakteristischen Funktion
Der Bruchpunkt
Für viele instrumentelle Verfahren ist es gängige Praxis, bei hohen Konzentrationen relative Messunsicherheiten anzugeben und bei kleinen Konzentrationen absolute Unsicherheiten. Viele Laboratorien fragen sich, wie die Grenzkonzentration ausgewählt werden kann. Der aus der charakteristischen Funktion errechente "Bruchpunkt" kann dafür genutzt werden, wobei angenommen wird, dass die Konzentrationsabhängigkeit der Präzision innerhalb des Labors vergleichbar ist zur Interlaborpräzision.
Konstante absolute Standardabweichung α bei niedrigen Konzentrationen
Ein ülicher Weg zur Berechnung der Bestimmungsgrenze ist BG = 10 · sr,0, wobei sr,0 die Wiederholstandardabweichung eines Leerwertes ist. Wenn wir - wie häufig getan wird - annehmen, dass die Wiederholstandardabweichung ungefähr die Hälfte der Vergleichstandardabweichung ist, dann können wir eine mittlere Bestimmungsgrenze der teilnehmenden Laboratorien aus LoQ = 10·sR,0/2 = 5·α abschätzen. Wo ein valider α-Wert aus den Ringversuchsdaten errechnet werden konnte, wird in der Tabell eine BG angegeben. In allen anderen Fällen ist angegeben, dass die BG kleiner als 5 mal die absolute Standardabweichung an der niedrigsten Konzentration ist.
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Bitte beachten Sie, dass die errechneten Bestimmungsgrenzen stark von den Konzentrationen der Proben abhängen, die im Ringversuch untersucht wurden. Hohe Konzentrationen führen auch zu hohen Bestimmungsgrenzen. Im Umkehrschluss können aus laborspezifischen Bestimmungsgrenzen auch α-Werte für die characteristische Funktion berechnet werden.
Konstante relative Standardabweichung β bei hohen Konzentrationen
In ISO 11352 und im NORDTEST technical report TR537 wird ein Verfahren zur Messunsicherheitsabschätzung beschrieben, dass die Präzisionskomponente und die Komponente der Unischerheit aufgrund systematischer Abweichungen separat quantifiziert und danach kombiniert. Für die Präzisionskomponente muss die Reproduzierbarkeit innerhalb des Labors abgeschätzt und als Standardabweichung uR,w quantifiziert werden. Wenn wir annehmen, dass die Wiederholstandardabweichung die Hälfte der Vergleichstandardabweichung beträgt, dann wird die mittlere Standardabweichung zur Beschreibung der Reproduzierbarkeit innerhalb des Labors ungefähr 0.8·sR betragen, und damit uR,w=0.8·β. Dieser Wert ist in unten stehender Tabelle auch angegeben. Wenn kein gültiger β-Wert abgeschätzt werden konnte, wird stattdessen ein Wert von < 0.8 mal dem Funktionswert bei der höchsten Konzentration angegeben. Dieser Wert für uR,w kann von Laboratorien zur Plausibilitätsprüfung ihrer eigenen Schätzungen genutzt werden.
Nutzung der charakteristischen Funktion zur Schätzung der Messunsicherheit über den gesamten Konzentrationsbereich
Nach ISO 21748 ist die erweiterte Unsicherheit, U, gleich 2·sR. Mit den Schätzwerten α und β kann die Unsicherheit jetzt über den gesamten Konzentrationsbereich mit Hilfe der charakteristischen Funktion bestimmt werden.
Gesetzliche Regelungen, wie z.B. die Europäische Richtlinie für Trinkwasser oder die Europäische Wasserrahmenrichtlinie, fordern, dass die genutzten analytischen Methoden bestimmte Anforderungen an die Unsicherheit erfüllen. Die charakteristische Funktion - mit ihren wie oben beschrieben abgeschätzten Parametern – zeigt, welche Messunsicherheit bei einem bestimmten Gehalt in der Realität im Mittel erreichbar ist.
1 Die Daten stammen von folgenden Quellen:
2 Thompson, M., Mathieson, K., Damant, A.P., and Wood, R.: A general model for interlaboratory precision accounts for statistics from proficiency testing in food analysis. Accred. Qual. Assur. (2008) 13:223-230).
3 Thompson, M, and Coles, B.J.: Examples of the ‘characteristic’ function applied to instrumental precision in chemical measurement. Accred. Qual. Assur. (2009) 14:147-150.
4 Thompson, M, and Coles, B.J.: Use of ‘characteristic function’ for modelling repeatability precision. Accred. Qual. Assur. (2011) 16:13-19.
Stand: 24.1.2013
| Parameter | Matrix | Methode |
|---|---|---|
| Parameter | Matrix | Methode | Einheit | n | cmin | cmax | α | β | Bruchpunkt | BG | uRw | Diagramm |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 2,4-D | drinking water | all | µg/l | 47 | 0.04916 | 0.7812 | 23.6128% | < 0.049 | < 0.077 | 24% | diagram | |
| 2,4-DB | drinking water | all | µg/l | 47 | 0.06016 | 0.8102 | 25.2347% | < 0.06 | < 0.1 | 25% | diagram | |
| 2,4,5-T | drinking water | all | µg/l | 47 | 0.06481 | 0.8081 | 23.6975% | < 0.065 | < 0.084 | 24% | diagram | |
| a-endosulfan | drinking water | all | µg/l | 14 | 0.0819 | 0.6118 | 19.627% | < 0.082 | < 0.08 | 20% | diagram | |
| desethylatrazine | drinking water | SPE-HPLC/UV | µg/l | 18 | 0.1191 | 0.710007 | 19.8424% | < 0.12 | < 0.17 | 20% | diagram | |
| desethylatrazine | drinking water | SPE-GC/MS | µg/l | 12 | 0.1191 | 0.710007 | < 0.12 | diagram | ||||
| chromium (VI) | drinking water | photometric | µg/l | 24 | 8.57576 | 59.2967 | 5.13272% | 18 | < 5.2 | 5.1% | diagram | |
| chromium | drinking water | ICP-OES | µg/l | 24 | 8.56836 | 102.613 | 6.11185% | 10 | < 4 | 6.1% | diagram | |
| chromium | drinking water | ICP-MS | µg/l | 22 | 8.56836 | 102.613 | 5.40861% | 16 | < 4.8 | 5.4% | diagram | |
| chlortoluron | drinking water | SPE-HPLC/UV | µg/l | 18 | 0.090561 | 0.812599 | 14.4397% | < 0.091 | < 0.084 | 14% | diagram | |
| chlortoluron | drinking water | SPE-HPLC/MS | µg/l | 13 | 0.095312 | 0.812599 | 18.622% | < 0.095 | < 0.089 | 19% | diagram | |
| chloroform | drinking water | GC-HS/MS | µg/l | 36 | 2.39117 | 16.0137 | 16.9851% | < 2.4 | < 2 | 17% | diagram | |
| chloride | drinking water | IC | mg/l | 33 | 20.9994 | 265.646 | 3.06496% | < 21 | < 4.3 | 3.1% | diagram | |
| calcium | drinking water | complexometric | mg/l | 13 | 50.8821 | 201.797 | 2.49529 | 2.09823% | 120 | 12 | 2.1% | diagram |
| calcium | drinking water | IC | mg/l | 16 | 50.3154 | 183.134 | 2.49811% | < 50 | < 6.7 | 2.5% | diagram | |
| cadmium | drinking water | ICP-OES | µg/l | 24 | 1.05057 | 10.1665 | 6.34721% | 1.5 | < 0.57 | 6.3% | diagram | |
| cadmium | drinking water | ICP-MS | µg/l | 23 | 1.05057 | 10.1665 | 7.32751% | < 1.1 | < 0.4 | 7.3% | diagram | |
| bromoform | drinking water | GC-HS/MS | µg/l | 36 | 2.2586 | 16.6764 | 16.1423% | 2.6 | < 2.7 | 16% | diagram | |
| bromoform | drinking water | GC-HS/ECD | µg/l | 36 | 2.32354 | 17.4056 | 15.1308% | < 2.3 | < 2.2 | 15% | diagram | |
| bromodichloromethane | drinking water | GC-HS/ECD | µg/l | 36 | 2.34338 | 15.7827 | 14.7467% | < 2.3 | < 1.9 | 15% | diagram | |
| boron | drinking water | ICP-OES | µg/l | 36 | 0.07942 | 1.48864 | 5.28623% | 0.19 | < 0.054 | 5.3% | diagram | |
| boron | drinking water | photometric | µg/l | 28 | 0.07942 | 1.48864 | 6.21303% | 0.29 | < 0.094 | 6.2% | diagram | |
| lead | drinking water | GF-AAS | µg/l | 33 | 4.86242 | 48.1076 | 12.1506% | < 4.9 | < 4.1 | 12% | diagram | |
| benzene | drinking water | GC-HS/FID | µg/l | 35 | 1.02161 | 9.06126 | 21.8658% | 1.2 | < 1.7 | 22% | diagram | |
| benzo(k)fluoranthene | drinking water | LLE-GC/MS | µg/l | 21 | 0.02782 | 0.205605 | 23.9527% | < 0.028 | < 0.042 | 24% | diagram | |
| benzo(k)fluoranthene | drinking water | LLE-HPLC | µg/l | 42 | 0.02782 | 0.205605 | 17.5228% | < 0.028 | < 0.029 | 18% | diagram | |
| benzo(ghi)perylene | drinking water | LLE-HPLC | µg/l | 42 | 0.027106 | 0.209578 | 25.7609% | < 0.027 | < 0.035 | 26% | diagram | |
| benzo(a)pyrene | drinking water | LLE-GC/MS | µg/l | 22 | 0.025597 | 0.209902 | 29.2347% | < 0.026 | < 0.037 | 29% | diagram | |
| benzo(a)pyrene | drinking water | LLE-HPLC | µg/l | 40 | 0.027617 | 0.230254 | 17.9993% | 0.028 | < 0.035 | 18% | diagram | |
| bentazone | drinking water | GC-MS | µg/l | 12 | 0.088812 | 0.859085 | < 0.089 | diagram | ||||
| atrazine | drinking water | SPE-GC/MS | µg/l | 13 | 0.095012 | 0.841144 | 18.4663% | < 0.095 | < 0.1 | 18% | diagram | |
| arsenic | drinking water | ICP-OES | µg/l | 19 | 2.88614 | 20.0852 | 17.6836% | 4.3 | < 4.6 | 18% | diagram | |
| antimony | drinking water | ICP-OES | µg/l | 18 | 2.38198 | 18.2842 | 24.9127% | < 2.4 | < 3 | 25% | diagram | |
| antimony | drinking water | ICP-MS | µg/l | 35 | 2.32285 | 19.0567 | 16.3964% | < 2.3 | < 2.1 | 16% | diagram | |
| ammonium | drinking water | CFA/FIA | mg/l | 26 | 0.229988 | 9.85749 | 0.0277819 | 5.07138% | 0.55 | 0.14 | 5.1% | diagram |
| antimony | drinking water | GF-AAS | µg/l | 17 | 2.32285 | 19.0567 | 22.2783% | 4.4 | < 5.5 | 22% | diagram | |
| aluminium | drinking water | ICP-MS | mg/l | 19 | 0.052985 | 0.197735 | 0.00492087 | 4.20545% | 0.12 | 0.025 | 4.2% | diagram |
| 1,2-dichloroethane | drinking water | GC-HS/MS | µg/l | 36 | 2.33736 | 15.4387 | 14.8407% | < 2.3 | < 1.7 | 15% | diagram | |
| magnesium | waste water | ICP-OES | µg/l | 12 | 5168 | 71763.6 | < 5170 | diagram | ||||
| calcium | waste water | ICP-OES | µg/l | 24 | 28869.9 | 140963 | 4.94434% | < 28870 | < 7140 | 4.9% | diagram | |
| boron | waste water | photometric | µg/l | 24 | 200.178 | 2065.82 | 7.7034% | 260 | < 120 | 7.7% | diagram | |
| boron | waste water | ICP-OES | µg/l | 24 | 185.235 | 1980.1 | 7.95759% | 460 | < 200 | 8% | diagram | |
| zinc | waste water | F-AAS | µg/l | 36 | 79.0161 | 4878.01 | 5.9182% | 190 | < 61 | 5.9% | diagram | |
| nickel | waste water | ICP-MS | µg/l | 5 | 96.58 | 871.625 | < 97 | diagram | ||||
| iron | waste water | AAS | µg/l | 38 | 119.286 | 3011.54 | 7.58598% | 250 | < 100 | 7.6% | diagram | |
| chromium | waste water | ICP-MS | µg/l | 5 | 54.12 | 970.88 | < 54 | diagram | ||||
| aluminium | waste water | ICP-OES | µg/l | 39 | 198.52 | 2073.13 | 8.2824% | 200 | < 120 | 8.3% | diagram | |
| dichloromethane | waste water | GC-HS/MS | µg/l | 42 | 23.955 | 1078.88 | 17.0058% | < 24 | < 20 | 17% | diagram | |
| 1,1,1-trichloroethane | waste water | GC-HS/ECD | µg/l | 42 | 12.2416 | 943.448 | 20.2319% | 14 | < 18 | 20% | diagram | |
| tetrachloroethene | waste water | GC-HS/ECD | µg/l | 42 | 12.3057 | 973.513 | 22.595% | < 12 | < 15 | 23% | diagram | |
| tetrachloroethene | waste water | GC-HS/MS | µg/l | 42 | 10.4133 | 1036.12 | 19.088% | < 10 | < 14 | 19% | diagram | |
| m-,p-xylene | waste water | GC-HS/MS | µg/l | 42 | 13.2101 | 1110.29 | 18.8158% | 19 | < 22 | 19% | diagram | |
| m-,p-xylene | waste water | GC-HS/FID | µg/l | 42 | 12.541 | 1108.28 | 15.7161% | 13 | < 14 | 16% | diagram | |
| o-xylene | waste water | GC-HS/MS | µg/l | 42 | 10.2775 | 1075.6 | 18.2013% | < 10 | < 11 | 18% | diagram | |
| o-xylene | waste water | GC-HS/FID | µg/l | 42 | 10.2314 | 1031.74 | 13.9594% | 14 | < 12 | 14% | diagram | |
| toluene | waste water | GC-HS/MS | µg/l | 42 | 12.3137 | 995.497 | 17.7837% | < 12 | < 13 | 18% | diagram | |
| total P | waste water | photometric - peroxodisulfate | mg/l | 30 | 0.626601 | 9.61304 | 3.52775% | < 0.63 | < 0.15 | 3.5% | diagram | |
| ammonium-N | waste water | CFA/FIA | mg/l | 49 | 1.98486 | 49.7542 | 4.51007% | 2.9 | < 0.8 | 4.5% | diagram | |
| ammonium-N | waste water | photometric | mg/l | 51 | 2.10414 | 49.9057 | 4.61178% | < 2.1 | < 0.5 | 4.6% | diagram | |
| COD | waste water | cuvette test | mg/l | 15 | 40.9943 | 198.716 | 5.34702% | < 41 | < 12 | 5.3% | diagram | |
| trichloroethene | waste water | all | µg/l | 69 | 12.907 | 985.588 | 19.2215% | < 13 | < 14 | 19% | diagram | |
| toluene | waste water | all | µg/l | 69 | 10.93 | 1000.16 | 14.7014% | 16 | < 14 | 15% | diagram | |
| TNb | waste water | all | mg/l | 93 | 9.19231 | 190.651 | 10.4872% | < 9.2 | < 6.6 | 10% | diagram | |
| nitrate-N | waste water | all | mg/l | 113 | 3.814 | 41.7278 | 3.78314% | < 3.8 | < 0.89 | 3.8% | diagram | |
| nickel | waste water | all | µg/l | 246 | 49.434 | 1029.82 | 6.50375% | 67 | < 27 | 6.5% | diagram | |
| dichloromethane | waste water | all | µg/l | 69 | 24.4044 | 1165.36 | 18.5893% | 25 | < 32 | 19% | diagram | |
| COD | waste water | all | mg/l | 189 | 28.998 | 266 | 3.34464 | 2.2668% | 150 | 17 | 2.3% | diagram |
| cadmium | waste water | all | µg/l | 239 | 0.519 | 11.18 | 14.4268% | 0.83 | < 0.71 | 14% | diagram | |
| arsenic | waste water | all | µg/l | 165 | 4.756 | 201.907 | 9.57217% | 11 | < 5.7 | 9.6% | diagram | |
| AOX | waste water | all | µg/l | 186 | 20.4901 | 1363.46 | 7.53144 | 9.19312% | 82 | 38 | 9.2% | diagram |
| 1,1,1-trichloroethane | waste water | all | µg/l | 69 | 11.798 | 981.669 | 20.1367% | < 12 | < 13 | 20% | diagram | |
| silicate | drinking water | all | mg/l SiO2 | 59 | 3.36197 | 50.9648 | 7.02702% | < 3.4 | < 1.4 | 7% | diagram | |
| selenium | drinking water | all | µg/l | 82 | 3 | 449.8 | 13.3559% | 6 | < 4.5 | 13% | diagram | |
| antimony | drinking water | all | µg/l | 101 | 2.3 | 423.8 | 14.0716% | 3.9 | < 3.2 | 14% | diagram | |
| p,p-DDD | drinking water | all | µg/l | 24 | 0.0245226 | 0.405836 | 23.1897% | 0.032 | < 0.046 | 23% | diagram | |
| lead | drinking water | all | µg/l | 77 | 4.8 | 90.5 | 9.81738% | 7.2 | < 4.2 | 9.8% | diagram | |
| tetrachloroethene | drinking water | all | µg/l | 90 | 0.5336 | 18.4875 | 19.5353% | < 0.53 | < 0.73 | 20% | diagram | |
| Permanganate index | drinking water | all | mg/l | 100 | 1.0262 | 21 | 0.287028 | 6.73837% | 4.3 | 1.4 | 6.7% | diagram |
| nitrate | drinking water | all | mg/l | 143 | 4.09 | 189.898 | 3.55012% | 10 | < 2 | 3.6% | diagram | |
| nickel | drinking water | all | µg/l | 77 | 5.9 | 89.8 | 7.12543% | 11 | < 4.4 | 7.1% | diagram | |
| ammonium | drinking water | all | mg/l | 130 | 0.084134 | 9.85749 | 6.05421% | 0.16 | < 0.056 | 6.1% | diagram | |
| manganese | drinking water | all | mg/l | 137 | 0.01606 | 0.664 | 6.51373% | 0.026 | < 0.0099 | 6.5% | diagram | |
| magnesium | drinking water | all | mg/l | 66 | 6.205 | 75.3308 | 4.24513% | < 6.2 | < 1.7 | 4.2% | diagram | |
| metolachlor | drinking water | all | µg/l | 33 | 0.074 | 0.755906 | 19.6353% | 0.084 | < 0.11 | 20% | diagram | |
| metobromurone | drinking water | all | µg/l | 30 | 0.0539 | 0.881281 | 17.0608% | < 0.054 | < 0.059 | 17% | diagram | |
| electrical conductivity | drinking water | all | µS/cm | 102 | 264.25 | 5387 | 1.29889% | < 260 | < 17 | 1.3% | diagram | |
| potassium | drinking water | all | mg/l | 102 | 1.549 | 37.536 | 5.10377% | 2.8 | < 0.82 | 5.1% | diagram | |
| ioxynil | drinking water | all | µg/l | 14 | 0.091 | 0.732 | 32.4875% | < 0.091 | < 0.15 | 32% | diagram | |
| Indeno(1,2,3-cd)pyrene | drinking water | all | µg/l | 85 | 0.013 | 0.257643 | 27.6168% | < 0.013 | < 0.018 | 28% | diagram | |
| mercury | drinking water | all | µg/l | 60 | 0.529873 | 11.58 | 12.0782% | 0.76 | < 0.56 | 12% | diagram | |
| heptachlor | drinking water | all | µg/l | 21 | 0.0417 | 0.488 | 30.047% | < 0.042 | < 0.063 | 30% | diagram | |
| g-HCH | drinking water | all | µg/l | 38 | 0.0273 | 0.6474 | 20.6667% | 0.041 | < 0.051 | 21% | diagram | |
| 1,2-dichloroethane | drinking water | all | µg/l | 83 | 1.4469 | 16.0758 | 18.1883% | 1.6 | < 2 | 18% | diagram | |
| dibromochloromethane | drinking water | GC-HS/ECD | µg/l | 36 | 2.42841 | 15.3528 | 15.5537% | < 2.4 | < 2.3 | 16% | diagram | |
| desethylatrazine | drinking water | SPE-HPLC/MS | µg/l | 8 | 0.122603 | 0.624626 | < 0.12 | diagram | ||||
| cyanide | drinking water | CFA/FIA | mg/l | 19 | 0.052589 | 0.124421 | 0.0172852 | > 0.12 | 0.086 | < 0.071% | diagram | |
| cyanide | drinking water | photometric | mg/l | 33 | 0.052589 | 0.133901 | 14.9521% | < 0.053 | < 0.051 | 15% | diagram | |
| chromium | drinking water | GF-AAS | µg/l | 25 | 8.56836 | 102.613 | 13.1203% | < 8.6 | < 6.2 | 13% | diagram | |
| chloroform | drinking water | GC-HS/ECD | µg/l | 36 | 2.39117 | 16.0137 | 14.1389% | 2.8 | < 2.6 | 14% | diagram | |
| chloride | drinking water | potentiometric | mg/l | 10 | 28.2734 | 265.646 | 50 | diagram | ||||
| calcium | drinking water | ICP-OES | mg/l | 30 | 50.3154 | 205.699 | 3.77399% | < 50 | < 9.5 | 3.8% | diagram | |
| calcium | drinking water | F-AAS | mg/l | 21 | 50.3154 | 201.797 | 4.62722% | < 50 | < 12 | 4.6% | diagram | |
| cadmium | drinking water | GF-AAS | µg/l | 34 | 1.05057 | 10.1665 | 12.5958% | < 1.1 | < 0.66 | 13% | diagram | |
| bromoxynil | drinking water | GC-MS | µg/l | 11 | 0.0929708 | 0.816355 | < 0.093 | diagram | ||||
| bromodichloromethane | drinking water | GC-HS/MS | µg/l | 36 | 2.34338 | 15.7827 | 15.481% | < 2.3 | < 1.9 | 15% | diagram | |
| bromate | drinking water | IC direct | µg/l | 33 | 0.007979 | 0.051366 | 38.6725% | < 0.008 | < 0.015 | 39% | diagram | |
| lead | drinking water | ICP-OES | µg/l | 24 | 4.86242 | 48.1076 | 9.27638% | 11 | < 5.7 | 9.3% | diagram | |
| lead | drinking water | ICP-MS | µg/l | 23 | 4.86242 | 48.1076 | 8.59458% | < 4.9 | < 2.9 | 8.6% | diagram | |
| benzene | drinking water | LLE-GC/MS | µg/l | 11 | 1.02161 | 9.06126 | < 1 | diagram | ||||
| benzene | drinking water | GC-HS/MS | µg/l | 36 | 1.02161 | 9.06126 | 14.816% | < 1 | < 1 | 15% | diagram | |
| benzo(ghi)perylene | drinking water | LLE-GC/MS | µg/l | 22 | 0.027106 | 0.209578 | 27.7921% | < 0.027 | < 0.047 | 28% | diagram | |
| benzo(b)fluoranthene | drinking water | LLE-GC/MS | µg/l | 22 | 0.025597 | 0.209902 | 29.2347% | < 0.026 | < 0.037 | 29% | diagram | |
| benzo(b)fluoranthene | drinking water | LLE-HPLC | µg/l | 42 | 0.025597 | 0.209902 | 18.2221% | < 0.026 | < 0.027 | 18% | diagram | |
| atrazine | drinking water | SPE-HPLC/UV | µg/l | 18 | 0.095012 | 0.841144 | 12.6499% | 0.12 | < 0.098 | 13% | diagram | |
| atrazine | drinking water | SPE-HPLC/MS | µg/l | 8 | 0.095012 | 0.743016 | < 0.095 | diagram | ||||
| arsenic | drinking water | ICP-MS | µg/l | 24 | 2.88614 | 20.0852 | 9.65414% | < 2.9 | < 1.8 | 9.7% | diagram | |
| arsenic | drinking water | H-AAS | µg/l | 23 | 2.88614 | 20.0852 | 10.0209% | 3.9 | < 2.4 | 10% | diagram | |
| arsenic | drinking water | GF-AAS | µg/l | 6 | 7.95015 | 18.4301 | < 8 | diagram | ||||
| antimony | drinking water | H-AAS | µg/l | 34 | 2.32285 | 19.0567 | 13.9962% | 3.1 | < 2.7 | 14% | diagram | |
| ammonium | drinking water | photometric | mg/l | 30 | 0.229988 | 9.85749 | 5.51091% | 0.31 | < 0.11 | 5.5% | diagram | |
| diurone | drinking water | all | µg/l | 60 | 0.0569 | 0.808719 | 17.4856% | < 0.057 | < 0.07 | 17% | diagram | |
| dimethoat | drinking water | all | µg/l | 9 | 0.077 | 0.212 | < 0.077 | diagram | ||||
| aluminium | drinking water | ICP-OES | mg/l | 21 | 0.052985 | 0.197735 | 9.46167% | 0.078 | < 0.045 | 9.5% | diagram | |
| 2,4-DP | drinking water | GC-MS | µg/l | 17 | 0.098226 | 0.874681 | 24.1815% | < 0.098 | < 0.12 | 24% | diagram | |
| 2,4-DB | drinking water | GC-MS | µg/l | 19 | 0.088748 | 0.755347 | 28.6484% | < 0.089 | < 0.13 | 29% | diagram | |
| 2,4-D | drinking water | GC-MS | µg/l | 19 | 0.085291 | 0.726167 | 30.8895% | < 0.085 | < 0.15 | 31% | diagram | |
| 2,4,5-T | drinking water | GC-MS | µg/l | 29 | 0.092629 | 0.726209 | 25.4434% | < 0.093 | < 0.14 | 25% | diagram | |
| 1,2-dichloroethane | drinking water | GC-HS/ECD | µg/l | 36 | 2.33736 | 16.6086 | 19.1175% | 3.6 | < 4.1 | 19% | diagram | |
| magnesium | waste water | F-AAS | µg/l | 12 | 5206 | 70197.3 | 7580 | diagram | ||||
| calcium | waste water | F-AAS | µg/l | 23 | 29391.3 | 145952 | 6.35926% | 36150 | < 14810 | 6.4% | diagram | |
| total P | drinking water | all | mg/l | 40 | 0.12649 | 5.35379 | 9.73123% | 0.16 | < 0.1 | 9.7% | diagram | |
| nitrite | drinking water | all | mg/l | 106 | 0.049 | 1.4447 | 4.73515% | 0.11 | < 0.029 | 4.7% | diagram | |
| sodium | drinking water | all | mg/l | 110 | 8.836 | 185.682 | 4.01896% | 12 | < 2.9 | 4% | diagram | |
| metribuzin | drinking water | all | µg/l | 30 | 0.068 | 1.0234 | 20.408% | < 0.068 | < 0.092 | 20% | diagram | |
| metazachlor | drinking water | all | µg/l | 15 | 0.119685 | 0.827 | 25.5564% | 0.12 | < 0.22 | 26% | diagram | |
| mecoprop | drinking water | all | µg/l | 61 | 0.05846 | 0.8464 | 20.2557% | 0.073 | < 0.095 | 20% | diagram | |
| MCPB | drinking water | all | µg/l | 47 | 0.06283 | 0.80781 | 22.744% | < 0.063 | < 0.073 | 23% | diagram | |
| MCPA | drinking water | all | µg/l | 61 | 0.0804047 | 0.88991 | 23.9452% | < 0.08 | < 0.11 | 24% | diagram | |
| linuron | drinking water | all | µg/l | 15 | 0.144978 | 0.68752 | 16.6377% | 0.19 | < 0.2 | 17% | diagram | |
| isoproturone | drinking water | all | µg/l | 60 | 0.059775 | 0.7742 | 17.4361% | 0.064 | < 0.076 | 17% | diagram | |
| hexachlorobenzene | drinking water | all | µg/l | 45 | 0.0184 | 0.522515 | 25.4413% | < 0.018 | < 0.029 | 25% | diagram | |
| fenoprop | drinking water | all | µg/l | 47 | 0.06969 | 0.8217 | 18.6181% | 0.074 | < 0.094 | 19% | diagram | |
| iron | drinking water | all | mg/l | 178 | 0.03106 | 2.788 | 6.27954% | 0.081 | < 0.027 | 6.3% | diagram | |
| fluoride | drinking water | all | mg/l | 104 | 0.3948 | 4.842 | 5.91368% | 0.75 | < 0.25 | 5.9% | diagram | |
| epichlorohydrine | drinking water | all | µg/l | 9 | 0.126353 | 0.98657 | < 0.13 | diagram | ||||
| endrin | drinking water | all | µg/l | 15 | 0.0259 | 0.460973 | 26.4601% | < 0.026 | < 0.044 | 26% | diagram | |
| dieldrin | drinking water | all | µg/l | 45 | 0.0267 | 0.56463 | 21.0729% | < 0.027 | < 0.038 | 21% | diagram | |
| dichlorprop | drinking water | all | µg/l | 61 | 0.0741 | 0.874681 | 20.3007% | < 0.074 | < 0.088 | 20% | diagram | |
| dibromochloromethane | drinking water | all | µg/l | 90 | 0.5938 | 24.1129 | 15.3661% | 0.76 | < 0.74 | 15% | diagram | |
| d-HCH | drinking water | all | µg/l | 15 | 0.0256 | 0.446872 | 27.0393% | < 0.026 | < 0.045 | 27% | diagram | |
| desisopropylatrazine | drinking water | all | µg/l | 18 | 0.155303 | 0.786547 | 26.8639% | < 0.16 | < 0.25 | 27% | diagram | |
| desethylatrazine | drinking water | all | µg/l | 45 | 0.0618 | 0.855 | 20.4529% | < 0.062 | < 0.065 | 20% | diagram | |
| copper | drinking water | all | µg/l | 110 | 21.0938 | 4452.1 | 5.28396% | 41 | < 12 | 5.3% | diagram | |
| cyanide | drinking water | all | mg/l | 68 | 0.009 | 0.133901 | 19.1364% | < 0.009 | < 0.012 | 19% | diagram | |
| chloride | drinking water | all | mg/l | 104 | 12.2483 | 289.636 | 2.90774% | 23 | < 3.7 | 2.9% | diagram | |
| chromium (VI) | drinking water | all | µg/l | 55 | 8.57576 | 88 | 5.57363% | 19 | < 5.8 | 5.6% | diagram | |
| chromium | drinking water | all | µg/l | 77 | 5.91 | 102.613 | 7.55565% | 6.9 | < 3.4 | 7.6% | diagram | |
| chlortoluron | drinking water | all | µg/l | 45 | 0.069 | 0.812599 | 15.4684% | < 0.069 | < 0.068 | 15% | diagram | |
| chloroform | drinking water | all | µg/l | 90 | 0.5634 | 22.3871 | 16.2495% | 0.89 | < 0.86 | 16% | diagram | |
| cadmium | drinking water | all | µg/l | 78 | 1.05057 | 51.7 | 8.0621% | 1.4 | < 0.71 | 8.1% | diagram | |
| calcium | drinking water | all | mg/l | 73 | 20.821 | 201.797 | 3.65416% | < 21 | < 4.3 | 3.7% | diagram | |
| bromoxynil | drinking water | all | µg/l | 61 | 0.06085 | 0.8781 | 26.3178% | < 0.061 | < 0.093 | 26% | diagram | |
| bromoform | drinking water | all | µg/l | 90 | 0.591 | 22.7734 | 16.1328% | 0.71 | < 0.74 | 16% | diagram | |
| bromodichloromethane | drinking water | all | µg/l | 89 | 0.5911 | 22.6431 | 14.8774% | < 0.59 | < 0.62 | 15% | diagram | |
| bromate | drinking water | all | mg/l | 68 | 0.0074 | 0.07 | 27.4636% | 0.0077 | < 0.015 | 27% | diagram | |
| benzene | drinking water | all | µg/l | 70 | 0.493 | 9.06126 | 20.2021% | < 0.49 | < 0.69 | 20% | diagram | |
| benzo(k)fluoranthene | drinking water | all | µg/l | 85 | 0.011 | 0.205605 | 19.9334% | 0.012 | < 0.016 | 20% | diagram | |
| benzo(ghi)perylene | drinking water | all | µg/l | 85 | 0.016 | 0.24 | 27.9337% | < 0.016 | < 0.022 | 28% | diagram | |
| benzo(b)fluoranthene | drinking water | all | µg/l | 85 | 0.008 | 0.2332 | 18.6636% | 0.0095 | < 0.012 | 19% | diagram | |
| benzo(a)pyrene | drinking water | all | µg/l | 85 | 0.005 | 0.230254 | 22.3934% | 0.0081 | < 0.011 | 22% | diagram | |
| bentazone | drinking water | all | µg/l | 61 | 0.06581 | 0.859084 | 22.7385% | < 0.066 | < 0.095 | 23% | diagram | |
| b-endosulfan | drinking water | all | µg/l | 14 | 0.0655 | 0.5632 | 19.0101% | < 0.066 | < 0.07 | 19% | diagram | |
| boron | drinking water | all | mg/l | 94 | 0.07942 | 1.94145 | 6.19642% | 0.23 | < 0.077 | 6.2% | diagram | |
| atrazine | drinking water | all | µg/l | 60 | 0.0567 | 0.833 | 15.4398% | < 0.057 | < 0.053 | 15% | diagram | |
| arsenic | drinking water | all | µg/l | 82 | 2.59565 | 278.7 | 9.6599% | 5.8 | < 3.1 | 9.7% | diagram | |
| aldrin | drinking water | all | µg/l | 39 | 0.0225322 | 0.676065 | 24.9853% | < 0.023 | < 0.037 | 25% | diagram | |
| a-HCH | drinking water | all | µg/l | 9 | 0.034 | 0.087 | 0.041 | diagram | ||||
| aluminium | drinking water | all | mg/l | 167 | 0.0345251 | 1.322 | 0.00957744 | 8.89197% | 0.11 | 0.048 | 8.9% | diagram |
| fenoprop | drinking water | GC-MS | µg/l | 20 | 0.084176 | 0.785141 | 22.6187% | < 0.084 | < 0.099 | 23% | diagram | |
| iron | drinking water | photometric | mg/l | 8 | 0.102486 | 0.631846 | 0.44 | diagram | ||||
| iron | drinking water | ICP-OES | mg/l | 21 | 0.098844 | 0.929647 | 5.48327% | < 0.099 | < 0.031 | 5.5% | diagram | |
| diurone | drinking water | SPE-HPLC/UV | µg/l | 18 | 0.085493 | 0.808719 | 0.017466 | 12.8522% | 0.14 | 0.087 | 13% | diagram |
| diurone | drinking water | SPE-HPLC/MS | µg/l | 13 | 0.085493 | 0.808719 | 19.0093% | < 0.085 | < 0.081 | 19% | diagram | |
| dibromochloromethane | drinking water | GC-HS/MS | µg/l | 36 | 2.34884 | 15.3528 | 15.4896% | < 2.3 | < 1.8 | 15% | diagram | |
| mercury | waste water | amalgam method | µg/l | 18 | 0.307063 | 10.0767 | 14.5003% | 0.57 | < 0.47 | 15% | diagram | |
| mercury | waste water | CV-AAS | µg/l | 39 | 0.380888 | 9.7982 | 0.114517 | 13.7644% | 0.83 | 0.57 | 14% | diagram |
| zinc | waste water | ICP-OES | µg/l | 39 | 77.7341 | 5037.29 | 6.19233% | 90 | < 37 | 6.2% | diagram | |
| nickel | waste water | AAS | µg/l | 38 | 55.7395 | 963.204 | 5.79866% | 110 | < 36 | 5.8% | diagram | |
| nickel | waste water | ICP-OES | µg/l | 39 | 55.9186 | 940.241 | 5.77758% | 67 | < 25 | 5.8% | diagram | |
| copper | waste water | AAS | µg/l | 38 | 44.9625 | 970.397 | 5.16444% | 120 | < 32 | 5.2% | diagram | |
| copper | waste water | ICP-OES | µg/l | 39 | 45.9481 | 929.62 | 5.41387% | < 46 | < 17 | 5.4% | diagram | |
| iron | waste water | ICP-OES | µg/l | 39 | 118.087 | 2985.04 | 5.27959% | 190 | < 58 | 5.3% | diagram | |
| chromium | waste water | AAS | µg/l | 38 | 53.85 | 975.167 | 12.3905% | 55 | < 48 | 12% | diagram | |
| chromium | waste water | ICP-OES | µg/l | 39 | 53.4151 | 983.249 | 5.7507% | < 53 | < 21 | 5.8% | diagram | |
| cadmium | waste water | GF-AAS | µg/l | 39 | 0.705921 | 9.54797 | 14.6086% | < 0.71 | < 0.63 | 15% | diagram | |
| cadmium | waste water | ICP-MS | µg/l | 18 | 0.911111 | 8.938 | 0.168575 | 7.41079% | 2.3 | 0.84 | 7.4% | diagram |
| cadmium | waste water | ICP-OES | µg/l | 37 | 0.74174 | 9.9072 | 16.7144% | < 0.74 | < 0.87 | 17% | diagram | |
| lead | waste water | GF-AAS | µg/l | 39 | 17.5439 | 211.419 | 12.2158% | 19 | < 16 | 12% | diagram | |
| lead | waste water | ICP-MS | µg/l | 15 | 22.3875 | 189.7 | 5.91536% | 54 | < 17 | 5.9% | diagram | |
| lead | waste water | ICP-OES | µg/l | 39 | 15.5648 | 207.81 | 7.56495% | 51 | < 20 | 7.6% | diagram | |
| arsenic | waste water | H-AAS | µg/l | 38 | 5.74756 | 198.194 | 11.2718% | 7.6 | < 5.4 | 11% | diagram | |
| arsenic | waste water | GF-AAS | µg/l | 14 | 5.32714 | 212.125 | 12.0735% | < 5.3 | < 4.5 | 12% | diagram | |
| arsenic | waste water | ICP-MS | µg/l | 14 | 24.125 | 182.885 | 9.32785% | < 24 | < 11 | 9.3% | diagram | |
| arsenic | waste water | ICP-OES | µg/l | 37 | 24.5936 | 193.4 | 9.14582% | 39 | < 21 | 9.1% | diagram | |
| aluminium | waste water | AAS | µg/l | 30 | 229 | 2123.68 | 16.0108% | 280 | < 290 | 16% | diagram | |
| dichloromethane | waste water | GC-HS/ECD | µg/l | 42 | 26.7004 | 1088.37 | 18.7921% | 28 | < 36 | 19% | diagram | |
| 1,1,1-trichloroethane | waste water | GC-HS/MS | µg/l | 42 | 11.9222 | 1050.7 | 19.6163% | < 12 | < 14 | 20% | diagram | |
| trichloroethene | waste water | GC-HS/ECD | µg/l | 42 | 13.8233 | 974.273 | 17.1634% | 15 | < 18 | 17% | diagram | |
| trichloroethene | waste water | GC-HS/MS | µg/l | 42 | 12.8143 | 1009.7 | 18.9611% | < 13 | < 12 | 19% | diagram | |
| ethylbenzene | waste water | GC-HS/MS | µg/l | 42 | 14.7067 | 1055.03 | 18.9048% | < 15 | < 15 | 19% | diagram | |
| ethylbenzene | waste water | GC-HS/FID | µg/l | 42 | 13.9842 | 1067.81 | 13.6767% | 16 | < 15 | 14% | diagram | |
| toluene | waste water | GC-HS/FID | µg/l | 42 | 12.3097 | 988.399 | 13.0065% | 22 | < 17 | 13% | diagram | |
| benzene | waste water | GC-HS/MS | µg/l | 42 | 12.6491 | 1087.49 | 18.1904% | < 13 | < 16 | 18% | diagram | |
| benzene | waste water | GC-HS/FID | µg/l | 42 | 13.1597 | 1061.41 | 13.8603% | 14 | < 13 | 14% | diagram | |
| chromium (VI) | waste water | photometric | mg/l | 15 | 0.152608 | 1.98554 | 3.59364% | < 0.15 | < 0.03 | 3.6% | diagram | |
| cyanide | waste water | CFA/FIA | mg/l | 15 | 0.208143 | 1.97723 | 0.0459552 | 11.046% | 0.42 | 0.23 | 11% | diagram |
| cyanide | waste water | distillation | mg/l | 30 | 0.271501 | 1.97742 | 12.2804% | 0.3 | < 0.25 | 12% | diagram | |
| cyanide, l.f. | waste water | CFA/FIA | mg/l | 16 | 0.13059 | 0.998222 | 0.0361258 | 10.192% | 0.35 | 0.18 | 10% | diagram |
| cyanide, l.f. | waste water | distillation | mg/l | 30 | 0.13074 | 0.944921 | 19.6844% | 0.14 | < 0.19 | 20% | diagram | |
| total P | waste water | photometric - nitric acid / sulfuric acid | mg/l | 23 | 0.600286 | 9.63762 | 3.26117% | 1 | < 0.19 | 3.3% | diagram | |
| total P | waste water | ICP-OES | mg/l | 45 | 0.55728 | 9.984 | 5.49133% | 0.64 | < 0.23 | 5.5% | diagram | |
| sulfate | waste water | IC | mg/l | 21 | 83.2519 | 481.12 | 3.20472% | < 83 | < 13 | 3.2% | diagram | |
| chloride | waste water | IC | mg/l | 21 | 70.118 | 495.13 | 3.23759% | < 70 | < 13 | 3.2% | diagram | |
| chloride | waste water | titrimetric | mg/l | 6 | 99.4667 | 446 | 160 | diagram | ||||
| nitrite-N | waste water | IC | mg/l | 36 | 0.116537 | 1.40002 | 7.40302% | 0.22 | < 0.091 | 7.4% | diagram | |
| nitrite-N | waste water | CFA/FIA | mg/l | 7 | 0.1306 | 1.37167 | 0.15 | diagram | ||||
| nitrite-N | waste water | photometric | mg/l | 42 | 0.114006 | 1.36429 | 2.913% | 0.14 | < 0.026 | 2.9% | diagram | |
| nitrate-N | waste water | photometric - DMP | mg/l | 21 | 4.67429 | 42.82 | 5.40695% | < 4.7 | < 1.5 | 5.4% | diagram | |
| nitrate-N | waste water | CFA/FIA | mg/l | 12 | 4.33661 | 38.0717 | 5.6 | diagram | ||||
| nitrate-N | waste water | IC | mg/l | 51 | 4.29789 | 41.6606 | 3.3687% | < 4.3 | < 0.72 | 3.4% | diagram | |
| ammonium-N | waste water | titrimetric | mg/l | 29 | 1.92125 | 48.97 | 0.306713 | 4.96003% | 6.2 | 1.5 | 5% | diagram |
| TOC | waste water | difference, therm-catalytic | mg/l | 24 | 11.0347 | 288.95 | 7.98698% | < 11 | < 4.6 | 8% | diagram | |
| TOC | waste water | direct, therm-catalytic | mg/l | 27 | 11.7345 | 292.283 | 4.6504% | < 12 | < 3.1 | 4.7% | diagram | |
| COD | waste water | open reflux method | mg/l | 45 | 29.903 | 191.854 | 3.22047 | 180 | 16 | < 1.8% | diagram | |
| AOX | waste water | microcolumn method | µg/l | 33 | 31.9177 | 899.322 | 7.1399 | 7.60524% | 94 | 36 | 7.6% | diagram |
| AOX | waste water | batch adsorption method | µg/l | 33 | 36.2596 | 913.767 | 10.1386 | 7.24001% | 140 | 51 | 7.2% | diagram |
| zinc | waste water | all | µg/l | 165 | 53.121 | 4949.51 | 5.85894% | 80 | < 28 | 5.9% | diagram | |
| TOC | waste water | all | mg/l | 186 | 10.302 | 299.037 | 4.88067% | 30 | < 7.8 | 4.9% | diagram | |
| tetrachloroethene | waste water | all | µg/l | 69 | 9.44 | 1004.4 | 20.8703% | < 9.4 | < 10 | 21% | diagram | |
| sulfate | waste water | all | mg/l | 62 | 34.865 | 485.294 | 3.68513% | 52 | < 12 | 3.7% | diagram | |
| total P | waste water | all | mg/l | 138 | 0.502 | 10.284 | 4.63675% | 0.7 | < 0.2 | 4.6% | diagram | |
| phenol index | waste water | all | µg/l | 75 | 25.2455 | 170.446 | 18.3077% | 31 | < 37 | 18% | diagram | |
| o-xylene | waste water | all | µg/l | 69 | 10.0662 | 1049.28 | 15.6313% | < 10 | < 10 | 16% | diagram | |
| nitrite-N | waste water | all | mg/l | 99 | 0.058 | 1.36502 | 3.94249% | 0.11 | < 0.025 | 3.9% | diagram | |
| m-,p-xylene | waste water | all | µg/l | 69 | 12.5112 | 1101.49 | 17.1732% | 17 | < 18 | 17% | diagram | |
| TPH | waste water | all | mg/l | 87 | 0.3 | 9.474 | 27.7521% | 0.46 | < 0.76 | 28% | diagram | |
| magnesium | waste water | all | mg/l | 42 | 1.02909 | 99.9229 | 4.83628% | < 1 | < 0.25 | 4.8% | diagram | |
| copper | waste water | all | µg/l | 217 | 42.195 | 1030.69 | 6.0973% | 68 | < 24 | 6.1% | diagram | |
| ethylbenzene | waste water | all | µg/l | 69 | 14.356 | 1061.72 | 16.3392% | < 14 | < 15 | 16% | diagram | |
| iron | waste water | all | mg/l | 164 | 0.09865 | 2.99043 | 6.21805% | 0.18 | < 0.065 | 6.2% | diagram | |
| cyanide, l.f. | waste water | all | mg/l | 50 | 0.117 | 0.951504 | 19.0748% | 0.19 | < 0.22 | 19% | diagram | |
| cyanide | waste water | all | mg/l | 51 | 0.161 | 1.97484 | 14.6845% | 0.26 | < 0.23 | 15% | diagram | |
| chromium (VI) | waste water | all | mg/l | 39 | 0.152608 | 1.98557 | 3.81279% | < 0.15 | < 0.036 | 3.8% | diagram | |
| chromium | waste water | all | µg/l | 246 | 47.628 | 1020.66 | 7.13698% | 48 | < 24 | 7.1% | diagram | |
| chloride | waste water | all | mg/l | 62 | 55.873 | 493.671 | 2.99682% | < 56 | < 11 | 3% | diagram | |
| calcium | waste water | all | mg/l | 83 | 2.71356 | 151.774 | 5.17021% | 2.9 | < 1 | 5.2% | diagram | |
| BOD5 | waste water | all | mg/l | 51 | 10.6993 | 179.568 | 14.7037% | < 11 | < 8.7 | 15% | diagram | |
| boron | waste water | all | µg/l | 84 | 106.358 | 2008.45 | 8.42737% | 320 | < 140 | 8.4% | diagram | |
| lead | waste water | all | µg/l | 244 | 14.643 | 426.032 | 11.1586% | 25 | < 16 | 11% | diagram | |
| benzene | waste water | all | µg/l | 69 | 12.123 | 1072.32 | 15.3615% | 14 | < 14 | 15% | diagram | |
| ammonium-N | waste water | all | mg/l | 112 | 1.849 | 56.352 | 4.70902% | 2.1 | < 0.66 | 4.7% | diagram | |
| aluminium | waste water | all | µg/l | 164 | 197.767 | 2083.64 | 8.60053% | 350 | < 170 | 8.6% | diagram | |
| turbidity | drinking water | all | FNU | 99 | 0.2954 | 8.609 | 0.0907134 | 8.7748% | 1 | 0.45 | 8.8% | diagram |
| trifluraline | drinking water | all | µg/l | 9 | 0.064 | 0.15 | < 0.064 | diagram | ||||
| trichloroethene | drinking water | all | µg/l | 90 | 0.3794 | 17.5987 | 19.338% | < 0.38 | < 0.51 | 19% | diagram | |
| TOC | drinking water | all | mg/l | 87 | 0.867794 | 23.2 | 0.247615 | 7.14005% | 3.5 | 1.2 | 7.1% | diagram |
| terbuthylazine | drinking water | all | µg/l | 60 | 0.0543 | 0.811724 | 17.5599% | < 0.054 | < 0.052 | 18% | diagram | |
| sulfate | drinking water | all | mg/l | 83 | 20.585 | 296.024 | 3.3258% | 27 | < 5.6 | 3.3% | diagram | |
| simazine | drinking water | all | µg/l | 39 | 0.07 | 0.875 | 19.1943% | < 0.07 | < 0.077 | 19% | diagram | |
| colour (436 nm) | drinking water | all | 1/m | 97 | 0.146905 | 1.961 | 0.0450104 | 7.87904% | 0.57 | 0.23 | 7.9% | diagram |
| propazine | drinking water | all | µg/l | 24 | 0.067 | 0.820257 | 15.1345% | 0.098 | < 0.09 | 15% | diagram | |
| p,p-DDT | drinking water | all | µg/l | 24 | 0.0232796 | 0.402616 | 28.9542% | < 0.023 | < 0.043 | 29% | diagram | |
| p,p-DDE | drinking water | all | µg/l | 21 | 0.0544 | 0.599 | 23.2255% | < 0.054 | < 0.065 | 23% | diagram | |
| o-phosphate | drinking water | all | mg/l | 28 | 0.381 | 11.2502 | 12.2158% | 0.39 | < 0.33 | 12% | diagram | |
| parathion-ethyl | drinking water | all | µg/l | 9 | 0.036 | 0.138 | < 0.036 | diagram | ||||
| fluoride | drinking water | IC | mg/l | 33 | 0.455874 | 2.54075 | 6.38356% | < 0.46 | < 0.21 | 6.4% | diagram | |
| fluoride | drinking water | ISE | mg/l | 33 | 0.455874 | 2.54075 | 5.21762% | 0.82 | < 0.25 | 5.2% | diagram | |
| total P | drinking water | photometric - peroxodisulfate | mg/l | 33 | 1.45479 | 5.35379 | 9.18985% | < 1.5 | < 0.67 | 9.2% | diagram | |
| total P | drinking water | ICP-OES | mg/l | 33 | 1.45479 | 5.35379 | 7.04403% | < 1.5 | < 0.58 | 7% | diagram | |
| Indeno(1,2,3-cd)pyrene | drinking water | LLE-HPLC | µg/l | 42 | 0.030575 | 0.257643 | 25.902% | < 0.031 | < 0.04 | 26% | diagram | |
| Indeno(1,2,3-cd)pyrene | drinking water | LLE-GC/MS | µg/l | 22 | 0.030575 | 0.257643 | 36.6753% | < 0.031 | < 0.056 | 37% | diagram | |
| isoproturone | drinking water | SPE-HPLC/MS | µg/l | 13 | 0.085306 | 0.768537 | 20.1575% | < 0.085 | < 0.086 | 20% | diagram | |
| isoproturone | drinking water | SPE-HPLC/UV | µg/l | 18 | 0.085306 | 0.768537 | 18.8099% | < 0.085 | < 0.1 | 19% | diagram | |
| potassium | drinking water | ICP-OES | mg/l | 21 | 2.92568 | 19.4673 | 5.34313% | < 2.9 | < 1.1 | 5.3% | diagram | |
| potassium | drinking water | F-AAS | mg/l | 15 | 2.92568 | 18.5473 | 5.31669% | 6.1 | < 1.8 | 5.3% | diagram | |
| potassium | drinking water | IC | mg/l | 9 | 3.78136 | 18.1044 | < 3.8 | diagram | ||||
| copper | drinking water | GF-AAS | µg/l | 22 | 21.0938 | 200.28 | 8.38243% | < 21 | < 8.8 | 8.4% | diagram | |
| copper | drinking water | ICP-MS | µg/l | 22 | 21.0938 | 200.28 | 5.51574% | 22 | < 8.5 | 5.5% | diagram | |
| copper | drinking water | ICP-OES | µg/l | 24 | 21.0938 | 200.28 | 5.37279% | 32 | < 10 | 5.4% | diagram | |
| electrical conductivity | drinking water | potentiometric | µg/l | 24 | 317.942 | 868.33 | 1.33912% | < 320 | < 23 | 1.3% | diagram | |
| magnesium | drinking water | F-AAS | mg/l | 22 | 8.24103 | 50.9923 | 4.01388% | < 8.2 | < 2.2 | 4% | diagram | |
| magnesium | drinking water | IC | mg/l | 18 | 8.24103 | 50.9923 | 3.48192% | < 8.2 | < 1.8 | 3.5% | diagram | |
| magnesium | drinking water | ICP-OES | mg/l | 30 | 8.24103 | 51.0167 | 4.02922% | < 8.2 | < 2 | 4% | diagram | |
| magnesium | drinking water | complexometric | mg/l | 12 | 8.24103 | 47.4579 | < 8.2 | diagram | ||||
| manganese | drinking water | ICP-MS | mg/l | 17 | 0.0204496 | 0.493994 | 5.04126% | < 0.02 | < 0.0052 | 5% | diagram | |
| manganese | drinking water | ICP-OES | mg/l | 21 | 0.0203501 | 0.485683 | 5.06131% | < 0.02 | < 0.0071 | 5.1% | diagram | |
| MCPA | drinking water | GC-MS | µg/l | 20 | 0.0899674 | 0.88991 | 30.1584% | < 0.09 | < 0.14 | 30% | diagram | |
| MCPB | drinking water | GC-MS | µg/l | 18 | 0.089511 | 0.788007 | 25.0948% | < 0.09 | < 0.14 | 25% | diagram | |
| mecoprop | drinking water | GC-MS | µg/l | 20 | 0.092967 | 0.770908 | 25.2955% | < 0.093 | < 0.13 | 25% | diagram | |
| metobromurone | drinking water | SPE-HPLC/MS | µg/l | 11 | 0.094549 | 0.783128 | < 0.095 | diagram | ||||
| metobromurone | drinking water | SPE-HPLC/UV | µg/l | 18 | 0.090397 | 0.881281 | 18.0824% | 0.099 | < 0.12 | 18% | diagram | |
| metribuzin | drinking water | SPE-GC/MS | µg/l | 10 | 0.10998 | 1.0234 | < 0.11 | diagram | ||||
| metribuzin | drinking water | SPE-HPLC/MS | µg/l | 8 | 0.109219 | 0.756078 | < 0.11 | diagram | ||||
| metribuzin | drinking water | SPE-HPLC/UV | µg/l | 18 | 0.109219 | 1.0234 | 18.9796% | 0.11 | < 0.15 | 19% | diagram | |
| sodium | drinking water | F-AAS | mg/l | 15 | 13.5224 | 148.109 | 3.61572% | < 14 | < 3 | 3.6% | diagram | |
| sodium | drinking water | IC | mg/l | 10 | 18.6453 | 135.478 | < 19 | diagram | ||||
| sodium | drinking water | ICP-OES | mg/l | 21 | 14.0988 | 148.445 | 4.59286% | 14 | < 4.6 | 4.6% | diagram | |
| nickel | drinking water | GF-AAS | µg/l | 29 | 10.1067 | 47.8225 | 8.29872% | < 10 | < 5.5 | 8.3% | diagram | |
| nickel | drinking water | ICP-MS | µg/l | 22 | 10.1067 | 46.9389 | 5.45095% | 18 | < 5.6 | 5.5% | diagram | |
| nickel | drinking water | ICP-OES | µg/l | 24 | 10.1067 | 47.8225 | 7.98184% | < 10 | < 4 | 8% | diagram | |
| nitrate | drinking water | photometric - DMP | mg/l | 9 | 14.5715 | 62.3371 | < 15 | diagram | ||||
| nitrate | drinking water | IC | mg/l | 33 | 6.10539 | 69.5405 | 3.43685% | 7.4 | < 1.7 | 3.4% | diagram | |
| nitrite | drinking water | CFA | mg/l | 8 | 0.185229 | 0.565595 | < 0.19 | diagram | ||||
| nitrite | drinking water | photometric | mg/l | 33 | 0.086803 | 0.606337 | 3.29624% | 0.2 | < 0.035 | 3.3% | diagram | |
| nitrite | drinking water | IC | mg/l | 33 | 0.086803 | 0.606337 | 0.0283901 | 8.51994% | 0.33 | 0.14 | 8.5% | diagram |
| propazine | drinking water | SPE-GC/MS | µg/l | 11 | 0.086819 | 0.820257 | < 0.087 | diagram | ||||
| propazine | drinking water | SPE-HPLC/MS | µg/l | 8 | 0.093525 | 0.694828 | < 0.094 | diagram | ||||
| propazine | drinking water | SPE-HPLC/UV | µg/l | 18 | 0.086819 | 0.820257 | 15.7456% | < 0.087 | < 0.096 | 16% | diagram | |
| mercury | drinking water | amalgam method | µg/l | 10 | 0.53 | 9.987 | 1 | diagram | ||||
| mercury | drinking water | CV-AAS/NaBH4 | µg/l | 21 | 0.53 | 9.987 | 0.140371 | 15.5052% | 0.91 | 0.7 | 16% | diagram |
| mercury | drinking water | CV-AAS/SnCl2 | µg/l | 30 | 0.53 | 9.987 | 9.92229% | 0.78 | < 0.47 | 9.9% | diagram | |
| selenium | drinking water | GF-AAS | µg/l | 13 | 6.2561 | 28.3803 | 20.4039% | 11 | < 12 | 20% | diagram | |
| selenium | drinking water | H-AAS | µg/l | 24 | 4.01217 | 30.4463 | 12.486% | < 4 | < 2.7 | 12% | diagram | |
| selenium | drinking water | ICP-MS | µg/l | 23 | 4.01217 | 30.4463 | 12.0467% | < 4 | < 2.7 | 12% | diagram | |
| selenium | drinking water | ICP-OES | µg/l | 22 | 4.01217 | 30.4463 | 2.6333 | 28 | 13 | < 9.2% | diagram | |
| silicate | drinking water | photometric | mg/l SiO2 | 24 | 5.31441 | 24.74 | 5.37966% | 9.2 | < 2.9 | 5.4% | diagram | |
| silicate | drinking water | ICP-OES | mg/l SiO2 | 24 | 5.31441 | 24.74 | 8.45247% | < 5.3 | < 2.9 | 8.5% | diagram | |
| simazine | drinking water | SPE-GC/MS | µg/l | 14 | 0.086788 | 0.757617 | 19.0471% | < 0.087 | < 0.1 | 19% | diagram | |
| simazine | drinking water | SPE-HPLC/MS | µg/l | 8 | 0.086788 | 0.757617 | 0.12 | diagram | ||||
| simazine | drinking water | SPE-HPLC/UV | µg/l | 18 | 0.086788 | 0.757617 | 17.2383% | < 0.087 | < 0.1 | 17% | diagram | |
| sulfate | drinking water | IC | mg/l | 33 | 32.6653 | 265.115 | 3.1736% | < 33 | < 5.7 | 3.2% | diagram | |
| terbuthylazine | drinking water | SPE-GC/MS | µg/l | 14 | 0.088324 | 0.811724 | 14.2925% | 0.099 | < 0.095 | 14% | diagram | |
| terbuthylazine | drinking water | SPE-HPLC/MS | µg/l | 8 | 0.088075 | 0.778466 | < 0.088 | diagram | ||||
| terbuthylazine | drinking water | SPE-HPLC/UV | µg/l | 18 | 0.088075 | 0.811724 | 18.4745% | < 0.088 | < 0.095 | 18% | diagram | |
| tetrachloroethene | drinking water | GC-HS/ECD | µg/l | 36 | 1.68379 | 10.4434 | 18.9679% | < 1.7 | < 2.2 | 19% | diagram | |
| tetrachloroethene | drinking water | GC-HS/MS | µg/l | 36 | 1.65909 | 10.4747 | 18.5182% | < 1.7 | < 1.8 | 19% | diagram | |
| trichloroethene | drinking water | GC-HS/ECD | µg/l | 36 | 1.76407 | 10.41 | 17.8414% | < 1.8 | < 1.9 | 18% | diagram | |
| trichloroethene | drinking water | GC-HS/MS | µg/l | 36 | 1.76407 | 10.2321 | 18.8691% | < 1.8 | < 1.7 | 19% | diagram | |
| mercury | waste water | all | µg/l | 87 | 0.205 | 9.8553 | 0.0945942 | 14.9828% | 0.63 | 0.47 | 15% | diagram |
| uranium | drinking water | all | µg/l | 10 | 1.31 | 17.45 | < 1.3 | diagram | ||||
| 2,4,5-T | drinking water | HPLC-MS/MS | µg/l | 5 | 0.124543 | 0.560022 | < 0.12 | diagram | ||||
| 2,4-D | drinking water | HPLC-MS/MS | µg/l | 6 | 0.0879491 | 0.738684 | < 0.088 | diagram | ||||
| boron | drinking water | ICP-MS | mg/l | 9 | 0.0808781 | 1.44517 | 0.21 | diagram | ||||
| bromoxynil | drinking water | HPLC-MS/MS | µg/l | 5 | 0.140702 | 0.818395 | < 0.14 | diagram | ||||
| dichlorprop | drinking water | HPLC-MS/MS | µg/l | 5 | 0.080405 | 0.739475 | < 0.08 | diagram | ||||
| Permanganate index | drinking water | titrimetric | mg/l | 24 | 1.71587 | 7.53845 | 0.448751 | > 7.5 | 2.2 | < 1.8% | diagram | |
| MCPA | drinking water | HPLC-MS/MS | µg/l | 6 | 0.10049 | 0.572047 | 0.12 | diagram | ||||
| mercury | drinking water | AFS | µg/l | 7 | 0.47201 | 6.48768 | < 0.47 | diagram | ||||
| colour (436 nm) | drinking water | photometric | 1/m | 21 | 0.146905 | 1.84722 | 0.0487882 | 11.3524% | 0.43 | 0.24 | 11% | diagram |
| TOC | drinking water | combustion | mg/l | 24 | 0.867794 | 10.4434 | 7.48661% | 2.3 | < 0.92 | 7.5% | diagram | |
| turbidity | drinking water | nephelometric | FNU | 33 | 0.629867 | 2.35154 | 10.3127% | 0.91 | < 0.57 | 10% | diagram |

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